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One limitation to orthodontics (ALL forms of orthodontics) is that it can only change the position of teeth. To control the size, color, shape, and APPEARANCE of teeth, porcelain veneers is really the only way (or full crowns). To get a natural result may require more than a single tooth, or not, so seek care from an experienced cosmetic dentist.
Thanks for submitting a photo. To me it actually looks like the left central tooth is too small....making the right look too big in proportion. It's is highly unusual to have the two centrals different sizes. I would definintily recommend seeing someone to determine what is going on. The left one could actually still be a baby tooth. To answer your question, Invisalign can ont do anything about tooth size. But a good orthodontist can help you figure out what is going on and the best way to fix it.