Yes, any restoration that is not sealing correctly will very likely give youproblems in the future this problem can be: increase of sensitivity cause bydentin exposure, accumulation of bacteria for the millimetric gap (not an easy accessto clean well) and therefor possible cavity formation.Pleasemake sure you have this problem fixed as soon as possible and, in the meanwhilebe extra careful with your brushing and hygiene technique.
It is unlikely, but yes it is possible depending on how long ago the veneers were done and your home care routine and brushing technique. If you are not brushing well at the gumline, debris and plaque can remain and cause decay. Keep in mind however that cavities do not develop overnight, it takes time.