My jaw hangs open naturally, I have overbite, TMJ, and asymmetry to name a few issues. What do you suggest I do? (Photo)

Hi there, your circumstances are interesting; however, without a proper examination, it is difficult to know why you are having discomfort.
As far as "maximizing your appearance," we would have to discuss in detail what your goals are for your looks.
Computer imaging will likely be needed to offer a more detailed recommendation. Please, email my staff so we can take a better look at your concerns and map out a plan for you.
Best regards,