I have crooked teeth, an overbite and an asymmetrical face. Can Invisalign fix this issue?

No, Invisalign will do little to nothing to improve your facial aesthetics. Adult maxillary arch development is your best course of treatment. This will improve your cheek bones, airway, nasolabial fold and TMJ. This can be accomplished with a number of effective appliances; including DNA, Homeoblock, SLDA, Shwarz, etc. The most important thing is not the appliance that is used but finding a doctor who knows how to effectively use an adult arch development appliance to accomplish what you desire.After arch development then it is possible that Invisalign can be used to effectively align your teeth.Good luck!

Consider Epigenetic Orthopedics with the DNA (mRNA) Appliance to correct the underlying Orthopedic issues.
Expansion or the maxilla will improve airway and create room for the mandible to advance with improvement to profile.
Ira L Shapira DDS, D,ABDSM, D,AAIPM, FICCMO, MICCMOPast Chair, Alliance of TMD Organizations    Diplomat,  Academy of Integrative Pain ManagementDiplomate, American Board of Dental Sleep MedicineDiplomate, American Board Sleep and BreathingRegent, Master & Fellow, International College of CranioMandibular OrthopedicsBoard Eligible, American Academy of CranioFacial PainDental Section Editor, Sleep & Health JournalCranioFacial Pain Section Editor, CRANIO: Journal of Craniomandibular and Sleep PracticeMember, American Equilibration SocietyMember, Academy of Applied Myofunctional SciencesMember, Academy of Cosmetic DentistryLife Member, American Dental Association