Can jawline and facial asymmetry be corrected? (Photo)

I am a perfectionist, however, my facial structure has bothered me since I was a teenager. When I smile I have what I call "jowels" that jut out from my jawline, and I think my chin and left side are uneven. Can this be corrected? Should I bother correcting it? Is my self assessment correct? I am only 105 lbs at 5'5" and I feel as though my jawline makes me look many lbs heavier.

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