Typically porcelain veneers are used to close gaps and hide spaces.
If you've had your teeth shift slightly after your veneers were done, then sometimes they can be moved slightly back into a tighter alignment. In this situation I work closely with my Orthodontist.
Most of the time there is not something that can be added to the porcelain to disguise the space. In rare cases there can be the right circumstances that some bonding could be done, but this is usually not the case.
If they used to fit tightly together and now there is a gap, then you will want to see your dentist right away to make sure it doesn't keep getting wider.
You could have a gum heath (periodontal disease) problem or a bite problem.